Tetrahedron Letters p. 2087 - 2088 (1989)
Update date:2022-07-29
Topics:
Bunz, Uwe
Szeimies, Guenter
Radical chain addition of 1,1,1-trichloroethane and, respectively, 1,1-dichloroethane to <1.1.1>-propellane led to bicyclo<1.1.1>pentane derivatives 5 and 6 which could be converted by sodium amide into the acetylenes 9 and 10.Glaser type coupling afforded the diacetylenes 12 and 13.
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Doi:10.1016/0022-328X(90)85137-N
(1990)Doi:10.1002/cmdc.201100002
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