Journal of Fluorine Chemistry p. 137 - 159 (1990)
Update date:2022-09-26
Topics:
Chen, Grace J.
Tamborski, Christ
Reactions between n-C6F13I, Cu and various bromoheterocyclic compounds in dimethyl sulfoxide provide a convenient method for the perfluoroalkylation of heterocyclic compounds.By this method perfluoroalkylated products of pyridine and pyrimidine were synthesized in near quantitative yields.Perfluoroalkylation of bromofurans and bromothiophenes also provided good yields of perfluoroalkylated products, however, competing reactions also yielded various by-products indicative of reductive dehalogenation, homocoupling, polysubstitution beyond the number of C-Br bonds in the starting heterocyclic compound and formation of structural isomers.
View MoreContact:+86-512-56795332
Address:No227 Shuanglong Rd, Fenghuang, Zhangjiagang
Wuhan Jadechem International Trade Co.,Ltd.
website:http://www.jadechem-intl.com
Contact:+86-27-83527060
Address:Room 502,Building C11,Software new city No.8,Huacheng Avenue,East Lake High-tech development zone,Wuhan,Hubei,China
Contact:13357117572
Address:No.149 Shiji dadao Road.
MS( MAOSHENG )Chemical CO.,LTD
Contact:+86-519-82726678.82726378
Address:TAOXI INDUSTRY ZONE JINTAN
website:http://www.mingchem.com/en/index
Contact:0519-85170101-802
Address:Fifth Floor,B of Beihua Buliding,520 Road of Science and Education City,Changwu middle road NO.801,Wujin District,Changzhou,Jiangsu province
Doi:10.1039/b810702e
(2008)Doi:10.1080/00397911.2020.1775852
(2020)Doi:10.1039/b801231h
(2008)Doi:10.1016/S0040-4039(00)85242-9
(1986)Doi:10.1039/c39840000914
(1984)Doi:10.1016/j.tetlet.2008.10.051
(2008)
