Journal of Fluorine Chemistry p. 137 - 159 (1990)
Update date:2022-09-26
Topics:
Chen, Grace J.
Tamborski, Christ
Reactions between n-C6F13I, Cu and various bromoheterocyclic compounds in dimethyl sulfoxide provide a convenient method for the perfluoroalkylation of heterocyclic compounds.By this method perfluoroalkylated products of pyridine and pyrimidine were synthesized in near quantitative yields.Perfluoroalkylation of bromofurans and bromothiophenes also provided good yields of perfluoroalkylated products, however, competing reactions also yielded various by-products indicative of reductive dehalogenation, homocoupling, polysubstitution beyond the number of C-Br bonds in the starting heterocyclic compound and formation of structural isomers.
View MoreJinhua City Mingzhu Pharmaceutical Co.,Ltd.
Contact:15857995878 0579-82207761
Address:No.169 Shenze Road, New Area,Jinpan Development Zone, Jinhua
Contact:86-27-84888681
Address:Wuhan economic & technology development zone
Xi'an yuanfar international trade company
website:https://www.yuanfarchemical.com
Contact:86-029-88745613 ext 828
Address:Floor19th ,B Building, Oak Block,No.36 South Fenghui Road, Dev. Zone of High-Tech Ind.,Xi’an, China
Contact:+86-574- 87178138; 87297407
Address:No. 809, Liudingxingzuo, cangsong road, Ningbo, China
Contact:86-15588110016
Address:LINYI CITY,SHANDONG PROVINCE,CHINA
Doi:10.1039/b810702e
(2008)Doi:10.1080/00397911.2020.1775852
(2020)Doi:10.1039/b801231h
(2008)Doi:10.1016/S0040-4039(00)85242-9
(1986)Doi:10.1039/c39840000914
(1984)Doi:10.1016/j.tetlet.2008.10.051
(2008)
