Journal of Fluorine Chemistry p. 137 - 159 (1990)
Update date:2022-09-26
Topics:
Chen, Grace J.
Tamborski, Christ
Reactions between n-C6F13I, Cu and various bromoheterocyclic compounds in dimethyl sulfoxide provide a convenient method for the perfluoroalkylation of heterocyclic compounds.By this method perfluoroalkylated products of pyridine and pyrimidine were synthesized in near quantitative yields.Perfluoroalkylation of bromofurans and bromothiophenes also provided good yields of perfluoroalkylated products, however, competing reactions also yielded various by-products indicative of reductive dehalogenation, homocoupling, polysubstitution beyond the number of C-Br bonds in the starting heterocyclic compound and formation of structural isomers.
View MoreContact:--
Address:80G, No.1 Building, Guodu Development Mansion, No. 182 Zhaohui Road, Hangzhou City, Zhejiang Province,China.
Shanggao Ruiya Fine Chemicals Co., Ltd
Contact:+86-795-2592103
Address:Xingguang Nanlu,Shanggao County Industry Park
Hunan Zhongqi Pharmaceutical Co., Ltd
website:http://www.hnzqzy.com
Contact:0730-8722288 13807308622
Address:Wanjiafan Road ,Yueyang Economic And Technological Development Zone ,Hunan,PRC
Yancheng Creator Chemical Co., Ltd
Contact:0086-515-88710008 88710068 88710858 88710868
Address:No.21 Renming Road, Longgang Town, Yandu County,Yancheng City
Airsea(Taizhou) Pharmaceutical Limited(expird)
Contact:+86-576-88057622
Address:Dubei, Duqiao, Linhai, Taizhou, Zhejiang, China Zip: 317016
Doi:10.1039/b810702e
(2008)Doi:10.1080/00397911.2020.1775852
(2020)Doi:10.1039/b801231h
(2008)Doi:10.1016/S0040-4039(00)85242-9
(1986)Doi:10.1039/c39840000914
(1984)Doi:10.1016/j.tetlet.2008.10.051
(2008)