On the Accessibility of cis-Bisphosphine Intermediates in Homogeneous Hydrogenation catalysed by Wilkinson's Complex, ClRh(PPh3)3

DOI: 10.1039/c39840000914

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 914 - 915 (1984)

Update date:2022-08-16

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Authors:

Brown, John M.

Lucy, Andrew R.

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Article abstract of DOI:10.1039/c39840000914

New information on the stereochemistry of intermediates in the catalytic cycle of hydrogenation by ClRh(PPh3)3 is revealed by magnetisation transfer experiments in 1H and 31P n.m.r. spectroscopy.

Full text of DOI:10.1039/c39840000914

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