Photoinduced Molecular Transformations. 110. Formation of Furoquinolinones via β-Scission of Cyclobutanoxyl Radicals Generated from Photoadducts of 4-Hydroxy-2-quinolone and Acyclic and Cyclic Alkenes. X-Ray Crystal Structure of (6aα,6bβ,10aβ,10bα)-

DOI: 10.1021/jo00303a034

Source and publish data:

Journal of Organic Chemistry p. 4933 - 4943 (1990)

Update date:2022-09-26

Topics:

Authors:

Suginome, Hiroshi

Kobayashi, Kazuhiro

Itoh, Masahito

Seko, Shinzo

Furusaki, Akio

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Article abstract of DOI:10.1021/jo00303a034

Several <2+2> photocycloadducts were prepared by the photoaddition of 4-acetoxy-2-quinolone or 4-hydroxy-N-methyl-2-quinolone with cyclic and acyclic olefins.The photoaddition of 4-acetoxy-2-quinolone with cyclopentene gave, exclusively, cis-cisoid-cis ad

Full text of DOI:10.1021/jo00303a034

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