An Oxidative/Reductive, Non-hydrolytic Procedure for 'Unravelling' Complex Acetals (Glycosides): a Possible Chemical Role for the exo-Anomeric Effect

DOI: 10.1039/c39870001462

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Journal of the Chemical Society. Chemical communications p. 1462 - 1464 (1987)

Update date:2022-07-29

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Authors:

Mootoo, David R.

Date, Vandana

Fraser-Reid, Bert

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Article abstract of DOI:10.1039/c39870001462

A non-hydrolytic procedure has been developed for cleavage of complex acetals/glycosides in which one of the acetal oxygen atoms undergoes oxidative, bromine-induced addition to a remote olefinic centre, with formation of a tetrahydrofuran ring, which is

Full text of DOI:10.1039/c39870001462

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