An Oxidative/Reductive, Non-hydrolytic Procedure for 'Unravelling' Complex Acetals (Glycosides): a Possible Chemical Role for the exo-Anomeric Effect

DOI: 10.1039/c39870001462

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1462 - 1464 (1987)

Update date:2022-07-29

Topics:

Authors:

Mootoo, David R.

Date, Vandana

Fraser-Reid, Bert

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39870001462

A non-hydrolytic procedure has been developed for cleavage of complex acetals/glycosides in which one of the acetal oxygen atoms undergoes oxidative, bromine-induced addition to a remote olefinic centre, with formation of a tetrahydrofuran ring, which is

Full text of DOI:10.1039/c39870001462

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:7,10-anhydro-2,3,5-tri-O-benzyl-11-bromo-4,6,8,10,11-pentadeoxy-4-C-(1'-formyl)-6-C-(1-methoxymethoxymethyl)-2,8,10-tri-C-methyl-D-(or L-)glycero-L-talo-L-altro-1',1-pyranose-undecitol

Cas No:128062-06-6

R&D Labs maybe for 128062-06-6

ZHUHAI HAIRUIDE BIOSCIENCE AND TECHNOLOGY CO.,LTD

website:http://www.zhhairuide.com

Contact:+8613326687259/+86-756-7789199

Address:No.10 Yonghui Road
Yixing Bluwat Chemicals Co., Ltd.

Contact:+86 510 87821568

Address:Yongan Road, Yixing Chemical Industrial Park, Yixing, Jiangsu, China
Chongqing KonAo Health Co.,Ltd

Contact:13687578375

Address:wuhan hubei china
Shanghai SMEC Trading Co., Ltd.

website:http://www.shanghaismec.com

Contact:+86-21-68811293

Address:ROOM 1101,NO.800 SHANGCHENG RD,SHANGHAI,CHINA
Hangzhou yi lu biont technology Co., LTD

Contact:+86-571-88152630

Address:Hangzhoushi HuafengRoad Yicheng3Building1001room.

Relevant to this article

Asymmetric catalytic C-H activation applied to the synthesis of syn-aldol products

Doi:10.1021/ol006671j
(2000)
Access to high levels of molecular complexity by one-pot iridium/enamine asymmetric catalysis

Doi:10.1002/anie.201007001
(2011)
General pathway for a convenient one-pot synthesis of trifluoromethyl- containing 2-amino-7-alkyl(aryl/heteroaryl)- 1,8-naphthyridines and fused cycloalkane analogues

Doi:10.3390/molecules16042817
(2011)
Positional isomeric effect of phenylenediacetate on the construction of mixed-ligand Cd^II coordination frameworks

Doi:10.1016/j.inoche.2011.01.029
(2011)
Silica gel-catalyzed air oxidation of cyclopentenones

Doi:10.1248/cpb.38.532
(1990)
TMSOTf-catalyzed synthesis of substituted quinazolines using hexamethyldisilazane as a nitrogen source under neat and microwave irradiation conditions

Doi:10.1039/d0ob01507e
(2020)

Article Doi