A Long-range Intramolecular Functionalization by Alkoxyl Radicals: a Long-range Intramolecular Hydroxylation of C(25) of Cholestane Side Chain

DOI: 10.1039/c39890001829

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Journal of the Chemical Society. Chemical communications p. 1829 - 1831 (1989)

Update date:2022-09-26

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Authors:

Orito, Kazuhiko

Satoh, Shinji

Suginome, Hiroshi

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Article abstract of DOI:10.1039/c39890001829

Alkoxyl radicals generated by the irradiation of hypoiodites of 5α-chloestan-7α-yl-4-(hydroxyphenylmethyl)phenylacetates and 5 α-cholestan-7α-yl-3-<4-(hydroxyphenylmethyl)phenyl> propionates, respectively, abstracted a hydrogen from the remote C(25) of th

Full text of DOI:10.1039/c39890001829

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