A Long-range Intramolecular Functionalization by Alkoxyl Radicals: a Long-range Intramolecular Hydroxylation of C(25) of Cholestane Side Chain

DOI: 10.1039/c39890001829

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1829 - 1831 (1989)

Update date:2022-09-26

Topics:

Authors:

Orito, Kazuhiko

Satoh, Shinji

Suginome, Hiroshi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39890001829

Alkoxyl radicals generated by the irradiation of hypoiodites of 5α-chloestan-7α-yl-4-(hydroxyphenylmethyl)phenylacetates and 5 α-cholestan-7α-yl-3-<4-(hydroxyphenylmethyl)phenyl> propionates, respectively, abstracted a hydrogen from the remote C(25) of th

Full text of DOI:10.1039/c39890001829

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:5α-cholestan-7α-yl 4-benzoylphenylacetate

Cas No:128098-05-5

R&D Labs maybe for 128098-05-5

Chengdu Boon Stream Chemical Industry Co.,Ltd.

Contact:+86-28-83156758

Address:No.859,Dongzikou Road,Jinniu District,Chengdu,Sichuan,P.R.China
Hebei DaPeng Pharm & Chem Co., Ltd.

Contact:86-317-7298678,0576-88861898 88861908

Address:West Songmen Village, East Songmen Town, Wuqiao, Cangzhou, Hebei ,China
Ceresking Ecology & Technology co.,ltd

Contact:86 22 66218397

Address:Room 1613, Zheshang Mansion, No. 1988, Yingbin Avenue, Binhai New District, Tianjin,China.
Daicel Chiral Technologies (China)CO.,LTD

Contact:021-5046-0086*8

Address:Part C, FL 5, the 16th Building, No. 69, XiYa Road, WaiGaoQiao Free Trade Zone, Shanghai, 200131, P.R.China
Shanghai Run-Biotech Co., Ltd.

website:http://www.run-biotech.com

Contact:+86-21-31576854/57171705 / 57171706

Address:second floor, building 3, No.999, jiangyue Road, minghang District, Shanghai, China

Relevant to this article

Propargylic carbonates as an a¹, a² synthon in annulation reactions. A convenient synthesis of 3-methylene dihydropyran derivatives

Doi:10.1016/S0040-4039(00)94347-8
(1990)
Negishi cross-coupling reaction as a simple and efficient route to functionalized amino and alkoxy carbene complexes of chromium, molybdenum, and Tungsten

Doi:10.1021/om500925m
(2014)
INSECT PHEROMONES AND THEIR ANALOGS. XXIV. METHYL-BRANCHED PHEROMONES DERIVED FROM 4-METHYLTETRAHYDROPYRAN. SYNTHESIS OF RACEMIC 14-METHYLOCTADEC-1-ENE - THE PHEROMONE OF Lyonetia clerckella

Doi:10.1007/BF00605210
(1990)
Molecular networks based on dative boron-nitrogen bonds

Doi:10.1002/anie.201007225
(2011)
Chemistry of heterocyclic ketene aminals: Construction of imidazo(pyrido)[1,2-a]pyridines and imidazo(pyrido)[3,2,1-ij][1,8]naphthyridines via DABCO-catalyzed tandem annulations

Doi:10.1021/jo102167g
(2011)
Synthesis of 3-Iodoquinolines by Copper-Catalyzed Tandem Annulation from Diaryliodoniums, Nitriles, and 1-Iodoalkynes

Doi:10.1002/adsc.201600081
(2016)

Article Doi