REGIO AND STEREOSELECTIVE PREPARATION OF SUBSTITUTED CYCLOPENTANONES FROM CYCLOHEXENONES UTILIZING TRIMETHYLSTANNYLLITHIUM AS A KEY REAGENT

DOI: 10.1016/S0040-4020(01)89517-X

Source and publish data:

Tetrahedron p. 6401 - 6408 (1989)

Update date:2022-08-03

Topics:

Authors:

Sato, Tadashi

Watanabe, Toshiyuki

Hayata, Toshihiro

Tsukui, Toru

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Article abstract of DOI:10.1016/S0040-4020(01)89517-X

3-Stannylcyclohexanones gave cyclopentanones via carbon-skeleton rearrangement with high regio and stereoselectivity, upon treatment with trimethylsilyl trifluoromethanesulfonate.

Full text of DOI:10.1016/S0040-4020(01)89517-X

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