UV-laser photochemistry: Retro-cleavage in the benzophenone-sensitized photolysis of Δ3-1,3,4-oxadiazolines into diazoalkanes

DOI: 10.1016/S0040-4039(00)94648-3

Source and publish data:

Tetrahedron Letters p. 863 - 866 (1990)

Update date:2022-08-04

Topics:

Authors:

Adam, Waldemar

Finzel, Ralf

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)94648-3

Triplet-sensitized photolysis of 2-methoxy-2,5,5-trimethyl-Δ³-1,3,4-oxadiazoline (1a) led to the retro-cleavage products diazoalkane 2a and the ester 3a, for which the triplet diazenyl diradical 6a is postulated as precursor.

Full text of DOI:10.1016/S0040-4039(00)94648-3

Products guided by the article

Product name:Acetic acid 3-cyclopropyl-3-methyl-2-phenyl-oxiranyl ester

Cas No:128103-55-9

R&D Labs maybe for 128103-55-9

TAIXING BEST NEW MATERIALS CO., LTD

Contact:0523-87998158;

Address:No.18 Zhonggang Road，Taixing City ，Jiangsu , China
Chengdu ZY Biochemical Technology Co., LTD

Contact:0086-28-88680086

Address:170 Qingpu Road, Shouan Town, Pujiang County
Feis International Trade Co,. Ltd

Contact:13961823444-18235944442

Address:Wuxi jiangsu
Chengdu Green technology Co.,Ltd.

Contact:86-28-82608355

Address:C9 ,Economic Headquarters, Economic Development Zone, Chengdu.
Cartoon Ingredients Co., Ltd

website:http://www.cartoonchem.com/

Contact:+86-25-58074918

Address:Room 2109, RuiHua Business Center,315 South ZhongShan Road, Nanjing 210001, China

Relevant to this article

Nickel-catalyzed reductive cleavage of aryl-oxygen bonds in alkoxy- and pivaloxyarenes using hydrosilanes as a mild reducing agent

Doi:10.1039/c0cc05169a
(2011)
Density and stability differences between enantiopure and racemic salts: Construction and structural analysis of a systematic series of crystalline salt forms of methylephedrine

Doi:10.1021/cg200030s
(2011)
Sulfonamidoglycosylation of Glycals. a Route to Oligosaccharides with 2-Aminohexose Subunits

Doi:10.1021/ja00171a021
(1990)
The resolution of trans-2,2-dichloro-3-methylcyclopropanecarboxylic acid via crystallization of its salts with (+)- and (-)-α-phenylethylamine, and the transformation of the resulting enantiomers into (R)- and (S)-dimethyl 2-methylsuccinates

Doi:10.1016/j.tetasy.2010.12.014
(2011)
Practical and efficient synthesis of N-fused tricyclic indoles

Doi:10.1016/j.tetlet.2010.10.155
(2011)
Gas-phase substituent effects in highly electron-deficient systems. II. stabilities of 1-aryl-2,2,2-trifluoroethyl cations based on chloride-transfer equilibria

Doi:10.1246/bcsj.70.1163
(1997)

Article Doi