Reduction of [1.1.1]propellane with lithium 4,4′-Di-t-butylbiphenyl: Bicyclo[1.1.1]pent-1,3-diyldilithium

DOI: 10.1016/S0040-4039(00)94592-1

Source and publish data:

Tetrahedron Letters p. 651 - 652 (1990)

Update date:2022-08-05

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Authors:

Bunz, Uwe

Szeimies, Guenter

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Article abstract of DOI:10.1016/S0040-4039(00)94592-1

[1.1.1]Propellane 1 has been reduced by 3 to 1,3-dilithiobicyclo[1.1.1]pentane (2b). which could be converted to some 1,3-disubstituted derivatives of 2a The reduction was also achieved with propellane 5. In addition, the synthesis oF the dialkyne 2i is reported.

Full text of DOI:10.1016/S0040-4039(00)94592-1

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