PHOTOOXYGENATION OF STRAINED EPOXIDES

DOI: 10.1016/S0040-4039(01)93356-8

Source and publish data:

Tetrahedron Letters p. 6801 - 6804 (1989)

Update date:2022-08-05

Topics:

Authors:

Palomino, Eduardo

Schaap, A. Paul

Heeg, Mary Jane

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Article abstract of DOI:10.1016/S0040-4039(01)93356-8

Photooxygenation of strained epoxides, type 1, in the presence of DCA or TCA afforded ozonide 2 in different ratios.A mechanism involving trapping of a radical cation by ³O2 is proposed.Trapping of an ylide intermediate by ¹O2 is also considered in the DCA-sensitized photooxygenation.

Full text of DOI:10.1016/S0040-4039(01)93356-8

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