PREPARATION AND RING-OPENING REACTIONS OF 2-PHENYLSULPHONYL-2-TRIMETHYLSILYL OXIRANES

DOI: 10.1016/S0040-4039(00)98809-9

Source and publish data:

Tetrahedron Letters p. 1877 - 1880 (1990)

Update date:2022-08-05

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Authors:

Hewkin, Cheryl T.

Jackson, Richard F. W.

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Article abstract of DOI:10.1016/S0040-4039(00)98809-9

Reaction of 2-phenylsulphonyl oxiranes (1) with butyllithium in the presence of chlorotrimethylsilane gave 2-phenylsulphonyl-2-trimethylsilyl oxiranes (2), which on treatment with MgBr2*Et2O gave 2-bromoacylsilanes (3) and either bromovinyl sulphones (5)

Full text of DOI:10.1016/S0040-4039(00)98809-9

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