Tetrahedron p. 6667 - 6678 (1989)
Update date:2022-08-05
Topics:
Schank, Kurt
Abdel Wahab, Aboel-Magd A.
Eigen, Peter
Jager, Juergen
Alkoxy arylsulfonyl carbenes 3 are generated by α elimination of hydrogen halide from (alkoxy)(halogeno)methyl aryl sulfones 1.Their self-decomposition as well as trapping reactions with diazoalkanes and with appropriate olefins are described.The structures of obtained cyclopropanes 21 and 23 are elucidated by 1H NMR methods.
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