Tetrahedron Letters p. 2617 - 2620 (1986)
Update date:2022-08-02
Topics:
Prandi, J.
Kagan, H. B.
Mimoun, H.
A practical procedure for the epoxidation of alkenes is described.The reaction is performed between 30 and 50 deg C in 1,2-dichloroethane with 30percent hydrogen peroxide and a catalytic amount of a quaternary phosphonium or ammonium pertungstate.Allylic alcohols are very reactive and require lower temperatures for their epoxidation.
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