Synthesis of Pyrrolizidines and Indolizidines by the Intramolecular Cycloaddition of Azides with Electron-Rich 1,3-Dienes. A Synthetic Equivalent of a Nitrene-Diene Cycloaddition

DOI: 10.1021/jo00309a016

Source and publish data:

Journal of Organic Chemistry p. 5719 - 5738 (1990)

Update date:2022-08-03

Topics:

Authors:

Pearson, William H.

Bergmeier, Stephen C.

Degan, Samir

Lin, Ko-Chung

Poon, Yam-Foo

et al. et al.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00309a016

Alkyl azides were found to undergo intramolecular cycloadditions with certain 1,3-dienes to provide 2,3,5,7a-tetrahydro-1H-pyrrolizines and 3,5,6,7,8,8a-hexahydroindolizines in one operation (e.g., 12 -> 13 and 17 -> 18).The presence of an electron-donati

Full text of DOI:10.1021/jo00309a016

Products guided by the article

Product name:(8R*,8aR*)-3,5,6,7,8,8a-Hexahydro-1-(phenylthio)-8-acetoxyindolizine

Cas No:128845-39-6

R&D Labs maybe for 128845-39-6

Anhui Xinyuan Technology Co.,Ltd

Contact:0086-559-3515800

Address:No.16 Zijin Rd, Circular Economic Zone, Huizhou District, Huangshan Anhui China
Deer Chemicals Co., Ltd.

Contact:+86-13666670345

Address:Agricultural Development Zone, Haining, Jiaxing, Zhejiang
Zouping Mingxing Chemical Co.,Ltd.

website:http://www.zoutong.com.cn

Contact:86-543-2240068 2240067

Address:428 Daixi Third Road Zouping County Shandong Province China
Tomo Pharma Chem Co., Limited

Contact:+86-158-05817090

Address:ROOM 9F, FLAT 2, GUODU DEVELOPING BLDG, No.182, ZHAOHUI ROAD
Hangzhou Bayee Chemical Co.,Ltd.

Contact:+86-571-86990109

Address:No.380, Jiangnan Auenue, Binjiang District, Hangzhou, China

Relevant to this article

Gold(I) complexes with alkylated PTA (1,3,5-triaza-7-phosphaadamantane) phosphanes as anticancer metallodrugs

Doi:10.1016/j.ejmech.2014.04.001
(2014)
Ruthenium(II) Complexes with the Atropisomeric Diphosphine 2,2'-Bis(diphenylphosphino)-6,6'-dimethylbiphenyl in the Enantioselective Hydrogenation of Pentane-2,4-dione

Doi:10.1039/DT9950000049
(1995)
Synthesis and recyclization reactions of 4-(o-R-phenyl)-3-imidazolines

Doi:10.1007/BF00717352
(1994)
(R)-n-menth-4-en-3-one and its derivatives in reactions with N-containing reagents

Doi:10.1007/s10600-014-0929-5
()
Synthesis and lanthanide coordination chemistry of phosphine oxide decorated dibenzothiophene and dibenzothiophene sulfone platforms

Doi:10.1021/ic500471w
(2014)
cis-trans-<(N3P3Cl4(C6H5)(PPh2))Mn(CO)2(bipy)(P(OPh)3)>PF6. A Cationic Manganese-Carbonyl Complex with a Phosphazenylphosphine Ligand

Doi:10.1107/S0108270194006943
(1995)

Article Doi