An asymmetric synthesis of the ant venom alkaloid (3S,5S,8aR)-3-butyl-5-(4-pentenyl)indolizidine via the sharpless asymmetric dihydroxylation

DOI: 10.3987/COM-95-S8

Source and publish data:

Heterocycles p. 39 - 42 (1996)

Update date:2022-08-03

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Authors:

Takahata, Hiroki

Bandoh, Hiroshi

Momose, Takefumi

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Article abstract of DOI:10.3987/COM-95-S8

The first asymmetric synthesis of the ant venom alkaloid (3S,5S,8aR)-3-butyl-5-(4-pentenyl)indolizidine (1) has been performed by starting with the Sharpless asymmetric dihydroxylation of N- alkenylcarbamate (3) followed by reductive annulation (5-exotetr

Full text of DOI:10.3987/COM-95-S8

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