Addition diastereoselective d'allyl cuprates a des imides chirales insaturees

DOI: 10.1016/0022-328X(90)85369-A

Source and publish data:

Journal of Organometallic Chemistry p. C5 - C8 (1990)

Update date:2022-08-03

Topics:

Authors:

Pourcelot, G.

Melnyk, O.

Besace, Y.

Stephan, E.

Cresson, P.

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Article abstract of DOI:10.1016/0022-328X(90)85369-A

Magnesium diallyl cuprate will add to unsaturated imides, synthesized from chiral imidazolidinones, with very high diastereoselectivity and good yields.Isoprenyl cuprate gives addition with lower yield and stereoselectivity.The products show total allylic inversion.

Full text of DOI:10.1016/0022-328X(90)85369-A

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