Addition diastereoselective d'allyl cuprates a des imides chirales insaturees

DOI: 10.1016/0022-328X(90)85369-A

Source and publish data:

Journal of Organometallic Chemistry p. C5 - C8 (1990)

Update date:2022-08-03

Topics:

Authors:

Pourcelot, G.

Melnyk, O.

Besace, Y.

Stephan, E.

Cresson, P.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(90)85369-A

Magnesium diallyl cuprate will add to unsaturated imides, synthesized from chiral imidazolidinones, with very high diastereoselectivity and good yields.Isoprenyl cuprate gives addition with lower yield and stereoselectivity.The products show total allylic inversion.

Full text of DOI:10.1016/0022-328X(90)85369-A

Products guided by the article

Product name:(4S,5R)-1-((R)-4,4-Dimethyl-3-phenyl-hex-5-enoyl)-3,4-dimethyl-5-phenyl-imidazolidin-2-one

Cas No:128863-76-3

R&D Labs maybe for 128863-76-3

Anhui Qingyun Pharmaceutical and Chemical Co.,Ltd

Contact:+86-551-63633067

Address:Shuangfeng Road Hefei Anhui
Zibo Xiaoguang Chemical Material Co., Ltd

Contact:15954099116

Address:Boshan Development Zone
Lonwin Chemical Group Limited

website:http://www.lonwinchem.com

Contact:Tel: 86-21-59858395

Address:No#966,Huaxu Road,Shanghai 201702,P.R.China
SuZhou Bichal Biological Technology CO.,LTD

Contact:+86-512-68051130

Address:NO.32 huoju road HI-TECH Industrial development zone SuZhou China
Yuan Shi(SuQian)Biotechnology Co.,Ltd

website:http://www.yuanshibio.com

Contact:+86-527-84226672

Address:jiangsu suqian

Relevant to this article

A concise and convergent synthesis of luotonin B and E

Doi:10.1055/s-0030-1259098
(2011)
α-Bromodiazoacetamides - a new class of diazo compounds for catalyst-free, ambient temperature intramolecular C-H insertion reactions

Doi:10.3762/bjoc.9.157
(2013)
An Unusual Cyclization Product from the Reaction of Citreamicin η with Sulfene

Doi:10.1021/jo00071a050
(1993)
Synthesis of acyclic tetrakis- and pentakis(N₂O₂) ligands for single-helical heterometallic complexes with a greater number of winding turns

Doi:10.1080/10610278.2010.514906
(2011)
First one-pot stereoselective synthesis of cis-2,3-dihydro-4- perfluoroalkyl-1H-1,5-benzodiazepines via a catalyst-free three-component reaction

Doi:10.1039/c0cc05039c
(2011)
Synthesis and coordination chemistry of 1-cymantrenyl-2,3,4,5- tetraphenylborole

Doi:10.1021/ic200559d
(2011)

Article Doi