Addition diastereoselective d'allyl cuprates a des imides chirales insaturees

DOI: 10.1016/0022-328X(90)85369-A

Source and publish data:

Journal of Organometallic Chemistry p. C5 - C8 (1990)

Update date:2022-08-03

Topics:

Authors:

Pourcelot, G.

Melnyk, O.

Besace, Y.

Stephan, E.

Cresson, P.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(90)85369-A

Magnesium diallyl cuprate will add to unsaturated imides, synthesized from chiral imidazolidinones, with very high diastereoselectivity and good yields.Isoprenyl cuprate gives addition with lower yield and stereoselectivity.The products show total allylic inversion.

Full text of DOI:10.1016/0022-328X(90)85369-A

Products guided by the article

Product name:(4S,5R)-1-((R)-4,4-Dimethyl-3-phenyl-hex-5-enoyl)-3,4-dimethyl-5-phenyl-imidazolidin-2-one

Cas No:128863-76-3

R&D Labs maybe for 128863-76-3

Taizhou volsen chemical Co., Ltd

website:http://www.volsenchem.com

Contact:+86-576-88869393

Address:Jiaojiang District, Taizhou, Zhejiang, China.
Hebei Maison Chemical Co.,Ltd

website:http://www.maisonchem.com.cn

Contact:0086-311-83833777

Address:Leitou industrial district, xinji, shijiazhuang city, hebei province,
Zhejiang kehong chemical co., ltd

Contact:0086-575-85522000

Address:xiner center RD binhai industrial zone shaoxing zhejiang province P.R.China,312073
Beyond Pharmaceutical Co., Ltd

Contact:+86-571-8195-3185

Address:No. 13-1, Liansheng Road, Yuhang District
BAODING SINO-CHEM INDUSTRY CO.,LTD

Contact:0312-5956088

Address:NO.8 FUXING ROAD,CHINA

Relevant to this article

A concise and convergent synthesis of luotonin B and E

Doi:10.1055/s-0030-1259098
(2011)
α-Bromodiazoacetamides - a new class of diazo compounds for catalyst-free, ambient temperature intramolecular C-H insertion reactions

Doi:10.3762/bjoc.9.157
(2013)
An Unusual Cyclization Product from the Reaction of Citreamicin η with Sulfene

Doi:10.1021/jo00071a050
(1993)
Synthesis of acyclic tetrakis- and pentakis(N₂O₂) ligands for single-helical heterometallic complexes with a greater number of winding turns

Doi:10.1080/10610278.2010.514906
(2011)
First one-pot stereoselective synthesis of cis-2,3-dihydro-4- perfluoroalkyl-1H-1,5-benzodiazepines via a catalyst-free three-component reaction

Doi:10.1039/c0cc05039c
(2011)
Synthesis and coordination chemistry of 1-cymantrenyl-2,3,4,5- tetraphenylborole

Doi:10.1021/ic200559d
(2011)

Article Doi