STEREOSELECTIVE ALDOL REACTIONS OF γ-THIOBUTYROLACTONE: THE BENZALDEHYDE ANOMALY.

DOI: 10.1016/S0040-4039(00)97387-8

Source and publish data:

Tetrahedron Letters p. 2453 - 2456 (1990)

Update date:2022-09-26

Topics:

Authors:

Gennari, Cesare

Oliva, Ambrogio

Molinari, Francesco

Piarulli, Umberto

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Article abstract of DOI:10.1016/S0040-4039(00)97387-8

Different protocols (lithium enolate reactions, fluoride catalyzed and Lewis acid mediated silyl ketene acetal reactions) were studied to achieve stereoselectivity in the aldol reactions of γ-thiobutyrolactone: in all cases benzaldehyde showed a striking

Full text of DOI:10.1016/S0040-4039(00)97387-8

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