Tetrahedron Letters p. 2277 - 2280 (1990)
Update date:2022-08-05
Topics:
Vatele, Jean-Michel
Dumas, Daniel
Gore, Jacques
In refluxing diglyme, the title α-hydroxy imines 7 and 8 rearrange cleanly to amino ketones 9 and 10 substituted on the carbon α to nitrogen by an allyl or a propargyl group.In the case of α-hydroxy imine 9, the migration of the allyl group occurs with an allylic transposition.
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