Chemical and Pharmaceutical Bulletin p. 515 - 524 (1996)
Update date:2022-09-26
Topics:
Tsuda, Yoshisuke
Murata, Masami
Hosoi, Shinzo
Ikeda, Mariko
Sano, Takehiro
Total syntheses of homoerythrinan alkaloids of 1(2)-alkene type, dihydroschelhammeridine and comosine, and those of 1,6-dienoid type, schelhammeridine and 3-epischelhammeridine, were achieved. Total synthesis of the former alkaloids provided definite proof of their A/B-cis stereochemistry. In relation to the stereochemistry, the conformations of erythrinan and homoerythrinan alkaloids are discussed.
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