Generation and Electrophilic Reactions of the 2,2,2-Trifluoro-1-(phenylthio)ethyl Carbocation

DOI: 10.1021/jo00306a013

Source and publish data:

Journal of Organic Chemistry p. 5364 - 5368 (1990)

Update date:2022-08-03

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Authors:

Uneyama, Kenji

Momota, Makoto

Hayashida, Kazuaki

Itoh, Toshiyuki

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Article abstract of DOI:10.1021/jo00306a013

2,2,2-Trifluoro-1-(phenylthio)ethyl carbocation (4) has been generated by the reaction of 1-chloro-2,2,2-trifluoroethyl phenyl sulfide (7b) with ZnCl2 in nitromethane or SnCl4 in 1,2-dichloroethane.The carbocation 4 can be trapped with various aromatics b

Full text of DOI:10.1021/jo00306a013

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