Generation and Electrophilic Reactions of the 2,2,2-Trifluoro-1-(phenylthio)ethyl Carbocation

DOI: 10.1021/jo00306a013

Source and publish data:

Journal of Organic Chemistry p. 5364 - 5368 (1990)

Update date:2022-08-03

Topics:

Authors:

Uneyama, Kenji

Momota, Makoto

Hayashida, Kazuaki

Itoh, Toshiyuki

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00306a013

2,2,2-Trifluoro-1-(phenylthio)ethyl carbocation (4) has been generated by the reaction of 1-chloro-2,2,2-trifluoroethyl phenyl sulfide (7b) with ZnCl2 in nitromethane or SnCl4 in 1,2-dichloroethane.The carbocation 4 can be trapped with various aromatics b

Full text of DOI:10.1021/jo00306a013

Products guided by the article

Product name:C₂₂H₁₅F₃O₂

Cas No:129286-64-2

R&D Labs maybe for 129286-64-2

Anhui Hope-Chem Co., Ltd.

Contact:86-551-63540590

Address:No 1388 Furong Rd., Hefei, Anhui, China
Shenzhen Hongyuan Import & Export Co., Ltd.

Contact:0755-26407171

Address:Shenzhen Hongyuan Chemical New Materials Technology Co., Ltd.
Evergreen Chemical Industry Ltd.

Contact:86-553-4918210

Address:6#2-602 Wanhaobailing
shijiazhuang shuanglian chemical industry co.,ltd

Contact:0311-82190302

Address:Luquan Intersection , Shijiazhuang--Taiyuan Expressway，Shijiazhuang City
Beijing Tianjia Chemical Science & Technology Co.,Ltd

Contact:86-0550-2392698

Address:No.388, Shiliang Road (East),

Relevant to this article

Some Diazinon Analogues Containing the 4-Trifluoromethyl Group

Doi:10.1007/BF00808930
(1990)
Synthesis of functionalized tetrahydroisoquinolines via palladium-catalyzed 6-exo-dig carbocyclization of 2-bromo-N-propargylbenzylamines

Doi:10.1016/j.tetlet.2011.01.127
(2011)
Pyrroloisoquinoline antidepressants. 3. A focus on serotonin

Doi:10.1021/jm00172a018
(1990)
Electrochemical Studies of Gold(I) and Gold(III) Complexes of Bis(diphenylphosphines)

Doi:10.1039/DT9900002219
(1990)
Design, synthesis and structure-activity relationship studies of a focused library of pyrimidine moiety with anti-proliferative and anti-metastasis activities in triple negative breast cancer

Doi:10.1016/j.ejmech.2017.08.067
(2017)
Synthesis of 1-[(1R)-1-(6-fluoro-1,3-benzothiazol-2-yl)ethyl]-3-substituted phenyl ureas and their inhibition activity to acetylcholinesterase and butyrylcholinesterase

Doi:10.1002/jhet.502
(2011)

Article Doi