Synthese von racemischem Acetyl(t-butyl)methylphenylsilan und Acetylmethylphenylsilan: Substrate fuer stereoselektive mikrobielle Reduktionen

DOI: 10.1016/0022-328X(90)85345-Y

Source and publish data:

Journal of Organometallic Chemistry p. 47 - 55 (1990)

Update date:2022-08-04

Topics:

Authors:

Tacke, Reinhold

Fritsche, Kirsten

Tafel, Andrea

Wuttke, Frank

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Article abstract of DOI:10.1016/0022-328X(90)85345-Y

The racemic acetyltriorganylsilanes MePh(Me3C)SiC(O)Me (1) and MePh(Me3SiCH2)SiC(O)Me (2) were prepared from MePhSiCl2.Compounds 1 and 2 are available by two different three-step synthesis.Method a: MePhSiCl2 -> MePh(Me3C)SiCl (5) -> (7) -> 1 (t

Full text of DOI:10.1016/0022-328X(90)85345-Y

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