Tandem anionic [3,3] sigmatropy and SN′ displacement. New synthetic technology for the construction of hydroazulenone and related frameworks

DOI: 10.1021/ja00179a037

Source and publish data:

Journal of the American Chemical Society p. 8478 - 8489 (1990)

Update date:2022-08-03

Topics:

Authors:

Paquette, Leo A.

Shi, Yao-Jun

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Article abstract of DOI:10.1021/ja00179a037

Transmetalation of the 3-(trimethylstannyl)-2-norcarenes 9 and 28b provides for the acquisition of optically pure bicyclic vinyllithium derivatives. These have been added to (±)-2-chlorocyclohexanone and the resultant cis-chlorohydrins have been exposed t

Full text of DOI:10.1021/ja00179a037

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