Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 1037 - 1044 (1990)
Update date:2022-08-05
Topics:
Kasatkin, A. N.
Tsypyshev, O. Yu.
Romanova, T. Yu.
Tolstikov, G. A.
Allyl Mn(II)-organic compounds R1CH=C(R2)CH2MnCl (R1 = H, Me; R2 = H, Me, Bu, PhCH2) react with esters and nitriles of crotonic, trans-2-hexenoic, sorbic, cinnamic, maleic, fumaric, heptylidenemalonic, and trans-(2-butenylidene)malonic acids in THF at -78 to -60 deg C giving 1,4-addition products.A single diastereomer is formed in the case of MeCH=CHCO2Me and PrCH=CHCO2Me.
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(1990)