?-COMPLEXES OF TRANSITION METALS IN ORGANIC SYNTHESIS: 8. COUPLED ADDITION OF ALLYL Mn(II)-ORGANIC COMPOUNDS TO ESTERS AND NITRILES OF α,β-UNSATURATED CARBOXYLIC ACIDS

DOI: 10.1007/BF00961710

Source and publish data:

Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 1037 - 1044 (1990)

Update date:2022-08-05

Topics:

Authors:

Kasatkin, A. N.

Tsypyshev, O. Yu.

Romanova, T. Yu.

Tolstikov, G. A.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1007/BF00961710

Allyl Mn(II)-organic compounds R¹CH=C(R²)CH2MnCl (R¹ = H, Me; R² = H, Me, Bu, PhCH2) react with esters and nitriles of crotonic, trans-2-hexenoic, sorbic, cinnamic, maleic, fumaric, heptylidenemalonic, and trans-(2-butenylidene)malonic acids in THF at -78 to -60 deg C giving 1,4-addition products.A single diastereomer is formed in the case of MeCH=CHCO2Me and PrCH=CHCO2Me.

Full text of DOI:10.1007/BF00961710

Products guided by the article

Product name:3-phenyl-4,5-dimethyl-5-hexenoic acid nitrile

Cas No:129433-24-5

R&D Labs maybe for 129433-24-5

qingdao goldenchem imp and exp co.,ltd.

Contact:532-55579246

Address:no.62 ,haier road laoshan distirct
Pale Palm Imex

Contact:+36(21)2523420

Address:Head office: 1102 Budapest, SZENT LASZLO TER 24/B. 1/1., HUNGARY / CHINA
EnBridge PharmTech Co., Ltd.

website:http://www.enbridgepharm.com

Contact:+86-510-83591909

Address:Huishan Zone, Wuxi City, Jiangsu Province, P.R.China
Kunming Biohome Technology Co. Ltd.

website:http://www.biohometech.com/

Contact:86-871-67428869

Address:kunming
BIOS CHEMICALS

Contact:+33-5-34012600

Address:28 ZA des Pignès

Relevant to this article

Substituted phenyl triazoles as selective inhibitors of 11β-hydroxysteroid dehydrogenase type 1

Doi:10.1016/j.bmcl.2011.01.125
(2011)
Synthesis, antibacterial and antimycobacterial activities of some new 4-aryl/heteroaryl-2,6-dimethyl-3,5-bis-N-(aryl)-carbamoyl-1,4-dihydropyridines

Doi:10.1016/j.ejmech.2011.02.003
(2011)
Synthesis and photophysical properties of alkynylated pyrimidines by site-selective sonogashira reactions of 2,4,5,6-tetrachloropyrimidine; First synthesis of tetraalkynyl-pyrimidines

Doi:10.1002/ejoc.201001622
(2011)
Optimization of allosteric MEK inhibitors. Part 1: Venturing into underexplored SAR territories

Doi:10.1016/j.bmcl.2013.02.028
(2013)
Theoretical investigation of the reaction of dialkylzincs with α-alkoxycarbonyl radicals. Evaluation of α-bromoacrylates as radical acceptors in radical-polar crossover processes

Doi:10.1016/j.tet.2015.09.045
(2015)
Synthesis of cytidyl(3′-5′)adenosine bearing 2′(3′)-O-leucyl ester via a phosphorothioate triester intermediate

Doi:10.1016/S0040-4020(01)86683-7
(1990)

Article Doi