
Organometallics p. 3001 - 3003 (1990)
Update date:2022-08-04
Topics:
Dufour
Dubac
Dartiguenave
Dartiguenave
1-Phenyl-2,3,4,5-tetramethyl-1-germacyclopentadienyl)lithium (4) was prepared by reaction of 1-phenyl-2,3,4,5-tetramethylgermole with n-butyllithium in THF/hexane at -70??C and chemically identified by electrophilic silylation and stannylation. A 13C NMR suggests that the negative charge in 4 is strongly localized on the germanium atom.
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Doi:10.1002/hlca.19900730414
(1990)Doi:10.1021/ol2008268
(2011)Doi:10.1007/s11172-010-0363-1
(2010)Doi:10.1021/ol200728w
(2011)Doi:10.1002/cbdv.201100007
(2012)Doi:10.1016/S0040-4020(01)88368-X
(1990)