Convenient Stereoselective Syntheses of (6E)- and (6Z)-5,6-Dimethyl-8-silyl-6-octenals

DOI: 10.1055/s-1990-26881

Source and publish data:

Synthesis p. 382 - 386 (1990)

Update date:2022-09-26

Topics:

Authors:

Asao, Kazuhiko

Iio, Hideo

Tokoroyama, T.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1055/s-1990-26881

A stereoselective synthetic method for the title compounds, E- and Z-allylsilanes, which would be generally applicable for the preparation of other trisubstituted allylsilanes, has been elaborated.The key steps are the following: (i) stereoselective prepa

Full text of DOI:10.1055/s-1990-26881

Products guided by the article

Product name:methyl (2Z)-8-benzyloxy-3-<(diethoxy)phosphoryloxy>-4-methyl-2-octenoate

Cas No:129512-07-8

R&D Labs maybe for 129512-07-8

Wuxi D-Stone International Co., Ltd.

Contact:+86-510-82740567

Address:21F Hengtong Int'l Centre, 215Zhongshan Road, Wuxi, Jiangsu,China
Zhongshan Haihong Medicine Co., Ltd.

Contact:86-0760-86925778 （0）18824993998

Address:A7 building,lianyuan road Torch Hi-tech Industrial Development Zone
Hubei anhuang chemical Co.Ltd

Contact:

Address:308# dongwu avenue dongxihu district wuhan city
GBXF SILICONES CO.,LTD

website:http://www.gbxfsilicones.com/

Contact:86-25-68900673

Address:He Country Provincial Fine Chemical Industrial Park of Chaohu city,Anhui province,China
NEW FORTUNE INDUSTRIAL CO.,LTD.

website:http://newfortune.lookchem.com/

Contact:+86-25-8645-9456

Address:C4-105 GREEN ISLAND FLOWER TOWN

Relevant to this article

Systematic investigations on the reduction of 4-aryl-4-oxoesters to 1-aryl-1,4-butanediols with methanolic sodium borohydride

Doi:10.3762/bjoc.6.94
(2010)
Lanthanide(II) complexes of a phosphine-borane-stabilised carbanion

Doi:10.1039/c001468k
(2010)
Intramolecular Mizoroki-Heck reaction in the regioselective synthesis of 4-alkylidene-tetrahydroquinolines

Doi:10.1002/ejoc.201300048
(2013)
Palladium(II) catalyzed Suzuki/Sonogashira cross-coupling reactions of sulfonates: An efficient approach to C2-functionalized pyrimidines and pyridines

Doi:10.1002/ejoc.201300592
(2013)
The influence of substitution of CO by PR3 on the photochemistry of Fe(CO)3(i-Pr2Ph-DAB) and Ru(CO)3(i-Pr2CH-DAB) (DAB=1,4-diaza-1,3-butadiene); a flash-photolysis and low-temperature study

Doi:10.1016/0022-328X(89)85290-8
(1989)
Synthesis and in vitro evaluation of 3H-pyrrolo[3,2-f]-quinolin-9-one derivatives that show potent and selective anti-leukemic activity

Doi:10.1002/cmdc.201000180
(2010)

Article Doi