Study of the reactivity of CpMCo(CO)7 (M = Mo, W) complexes toward various alkynes

DOI: 10.1021/om00161a032

Source and publish data:

Organometallics p. 2998 - 3001 (1990)

Update date:2022-08-05

Topics:

Authors:

Yanez Yanez

Lugan Lugan

Mathieu Mathieu

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Article abstract of DOI:10.1021/om00161a032

The CpMCo(CO)₇ complexes (M = Mo, W) react with alkynes in boiling hexane, leading to CpMCo(CO)₅(μ-η²,η²-RC≡CR′) complexes (M = Mo, R = R′ = H, Ph, SiMe₃, C(O)OMe; M = Mo, R = H, R′ = SiMe₃

Full text of DOI:10.1021/om00161a032

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