Tetrahedron Letters p. 1689 - 1692 (1990)
Update date:2022-09-26
Topics:
Ulbrich
Famulok
Bosold
Boche
The model reaction of 5 with 6 to give 7 and 8 (≥90%) follows the S(N)2 mechanism. From this result and from product studies it is concluded that the reactions of the ultimate carcinogen 1 with 6 and deoxyguanosine (dG) (and hence of other ultimate carcinogens of aromatic amines with bionucleophiles) follow the same mechanism.
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