Tetrahedron Letters p. 3429 - 3432 (1990)
Update date:2022-08-05
Topics:
Ehle, Michael
Wagner, Oliver
Bergstraesser, Uwe
Regitz, Manfred
1-Halo- and 1-cyano-1H-phosphirenes 8a-d react with tetrachloro-o-quinone (9) by oxidative addition at phosphorus to furnish the previously unknown title compounds 10a-d.The chlorine atom in the pentacoordinated phosphirene 10a undergoes nucleophilic exchange reactions yielding 10c-e.
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