Mechanistic Insight into Allylmetal-Thioacetal Reactions Employing 2-Acetoxy-2-phenylacetaldehyde Thioacetals

DOI: 10.1021/jo00312a016

Source and publish data:

Journal of Organic Chemistry p. 6116 - 6121 (1990)

Update date:2022-09-26

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Authors:

Sato, Tsuneo

Otera, Junzo

Nozaki, Hitosi

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Article abstract of DOI:10.1021/jo00312a016

The mechanism of allyl-metal-thioacetal reactions has been investigated by using 2-acetoxy-2-phenylacetaldehyde thioacetals in the presence of trimethylsilyl triflate.The results unambiguously revealed the occurence of both S_N1- and S_{N
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Full text of DOI:10.1021/jo00312a016

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