
Journal of Organic Chemistry p. 5808 - 5810 (1990)
Update date:2022-09-26
Topics:
Friesen, Richard W.
Sturino, Claudio F.
The synthesis of the C-arylglucoside tricyclic spiroketal nucleus of the papulacandins 5b was achieved utilizing two key steps, namely the palladium-catalyzed coupling of the aryl bromide 6 and the stannyl glucal 2 and stereoselective oxidative spiroketal
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