Chemistry Letters p. 933 - 936 (1987)
Update date:2022-08-02
Topics:
Tachibana, Masahiko
Tero-Kubota, Shozo
Iwaizumi, Masamoto
1,4-Dihydroxyanthraquinone, a model compound for Adriamycin, is reduced by Fe2+-ADP complex to generate semiquinone, while by Fe2+-phosphate complex to hydroquinone.The difference is explained in terms of the higher redox potential of the latter reducing agent.Similar reduction reactions were observed in the case of the drug.
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