A Convenient Method for Stereoselective Synthesis of β-Aminoesters. Iron(II) Iodide or Trityl Hexachloroantimonate as an Effective Catalyst in the Reaction of Ketene Silyl Acetals with Imines

DOI: 10.1246/cl.1990.889

Source and publish data:

Chemistry Letters p. 889 - 892 (1990)

Update date:2022-08-03

Topics:

Authors:

Mukaiyama, Teruaki

Akamatsu, Hidekazu

Han, Jeong Sik

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1990.889

In the presence of a catalytic amount of iron(II) iodide or trityl hexachloroantimonate, ketene silyl acetals smoothly react with imines to afford the corresponding β-aminoesters in good yields with anti-selectivities.

Full text of DOI:10.1246/cl.1990.889

Products guided by the article

Product name:(2R,3R)-2-Methyl-3-phenylamino-3-thiophen-2-yl-propionic acid methyl ester

Cas No:129823-51-4

R&D Labs maybe for 129823-51-4

Hangzhou Yingshanhua Pigment Chemicals Co.,Ltd.

Contact:+86-0150-58101658

Address:Nanyang Economic DevelopmentZong,Xiaoshan,Hangzhou,China
Suzhou Zhonghelong Chemical Tech Co., Ltd【License cancellation】

Contact:+86 571-12345678

Address:Dunhuang Road, Suzhou Industrial Park, No.128 building 701 room Mansion
Shijiazhuang City Xiehe Pharmaceutical Co., Ltd

Contact:+86-311-80817929

Address:Shangzhuang,Shijiazhuang,China
SICHUAN ZHONGBANG NEW MATERIAL CO., LTD

website:http://www.zhongbangst.com

Contact:86-830-2585019

Address:sichuan,china
Jinzhou Jiutai Pharmaceutical Co.,Ltd

Contact:+86-0416-5179890

Address:No.41, Taianli, Taihe District, Jinzhou, Liaoning

Relevant to this article

(Benzoyliodomethyl)triphenylphosphonium Iodide: A Convenient Reagent for Direct Synthesis of Arylethynyl Phenyl Ketones by Chain Extension of Aldehydes

Doi:10.1055/s-1990-26964
(1990)
SELECTIVE ALKYLATION OF IMIDAZOLE-4(5)-CARBOXAMIDES

Doi:10.1007/BF00497210
(1990)
KINETICS OF REARRANGEMENT OF 2,4-DICHLOROPHENYL(1H-1,2,4-TRIAZOL-1-YLMETHYL)KETONE ENOL ACETATE

Doi:10.1007/BF00863809
(1992)
TMSOTf-Promoted Sulfinylation of Electron-Rich Aromatics with Sodium Arylsulfinates

Doi:10.1055/s-0039-1691563
(2020)
SYNTHESIS OF THE CARBAPENAM RING SYSTEM VIA CARBENE MEDIATED REARRANGEMENT OF AN N-BENZYLOXY-β-LACTAM

Doi:10.1016/S0040-4039(00)98791-4
(1990)
Cesium-catalyzed highly regioselective synthesis of (Z)-vinylic selenosulfides via thioselenation of alkynes with unsymmetrical diorganoyl dichalcogenides

Doi:10.1016/j.tet.2017.04.009
(2017)

Article Doi