A Convenient Method for Stereoselective Synthesis of β-Aminoesters. Iron(II) Iodide or Trityl Hexachloroantimonate as an Effective Catalyst in the Reaction of Ketene Silyl Acetals with Imines

DOI: 10.1246/cl.1990.889

Source and publish data:

Chemistry Letters p. 889 - 892 (1990)

Update date:2022-08-03

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Authors:

Mukaiyama, Teruaki

Akamatsu, Hidekazu

Han, Jeong Sik

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Article abstract of DOI:10.1246/cl.1990.889

In the presence of a catalytic amount of iron(II) iodide or trityl hexachloroantimonate, ketene silyl acetals smoothly react with imines to afford the corresponding β-aminoesters in good yields with anti-selectivities.

Full text of DOI:10.1246/cl.1990.889

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