SYNTHESIS OF THE CARBAPENAM RING SYSTEM VIA CARBENE MEDIATED REARRANGEMENT OF AN N-BENZYLOXY-β-LACTAM

DOI: 10.1016/S0040-4039(00)98791-4

Source and publish data:

Tetrahedron Letters p. 1807 - 1810 (1990)

Update date:2022-08-03

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Authors:

Williams, Matthew A.

Miller, Marvin J.

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Article abstract of DOI:10.1016/S0040-4039(00)98791-4

The α-diazoester 1 in the presence of catalytic Rh2(OAc)4 was converted to the carbapenam 2.The synthesis of 1 and a proposed mechanism are described.

Full text of DOI:10.1016/S0040-4039(00)98791-4

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