Syntheses and Characterization of Stable Pseudo-octahedral Tris-phenolato Complexes of Vanadium-(III), -(IV), and -(V)

DOI: 10.1039/c39900001004

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1004 - 1006 (1990)

Update date:2022-08-02

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Authors:

Auerbach, Ulf

Della Vedova, Beatrice S. P. C.

Wieghardt, Karl

Nuber, Bernhard

Weiss, Johannes

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Article abstract of DOI:10.1039/c39900001004

Reaction of the anionic form of the hexadentate ligand 1,4,7-tris(5-t-butyl-2-hydroxybenzyl)-1,4,7-triazacyclononane (H3L) with VCl3 in MeCN affords LV^III which is oxidized chemically and electrochemically to IV>(1+) and V>(2+); electrochemical, magnetic, and electronic spectroscopic properties of these complexes and the X-ray structure of are reported.

Full text of DOI:10.1039/c39900001004

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