Tetrahedron p. 5067 - 5078 (1993)
Update date:2022-08-04
Topics:
Marschner
Penn
Griengl
Both α- and β-D,L-ribo-carbahex-2-ulofuranose have been synthesized in racemic form starting from norbornen-2-one. In the course of the synthesis the reaction of sulfur ylides with α-alkoxyketones took an unexpected stereochemical pathway.
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