NOREPHEDRINE DERIVED 2-METHOXY OXAZOLIDINES AS CHIRAL FORMYL CATION EQUIVALENTS

DOI: 10.1016/S0040-4039(00)94697-5

Source and publish data:

Tetrahedron Letters p. 2779 - 2782 (1990)

Update date:2022-09-26

Topics:

Authors:

Bernardi, Anna

Cardani, Silvia

Carugo, Oliviero

Colombo, Lino

Scolastico, Carlo

Villa, Roberto

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Article abstract of DOI:10.1016/S0040-4039(00)94697-5

Lewis acid catalyzed reaction of silylenolethers with 1 followed by a straightforward nondestructive removal of the chiral auxiliary affords the corresponding aldehydes in good e.e.Compound 1 respresents the first effective synthetic equivalent of formyl cation.

Full text of DOI:10.1016/S0040-4039(00)94697-5

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