Hydrogenation and Dimerization of Bicyclohepta-2,5-diene Catalyzed by Cobalt(I) Complexes

DOI: 10.1246/bcsj.59.1277

Source and publish data:

Bulletin of the Chemical Society of Japan p. 1277 - 1278 (1986)

Update date:2022-09-26

Topics:

Authors:

Kanai,Hiroyoshi

Watabe, Yoshiyuki

Nakayama, Taisei

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/bcsj.59.1277

Bicyclo<2,2,1>hepta-2,5-diene 1 was hydrogenated to bicyclo<2,2,1>hept-2-ene 2 and tricyclo<2.2.1.0^2,6>heptane 3 in a 70:30 ratio and dimerized to Binor-S 4 by -BF3*Et2O catalysts (X = halogen). 1 was dimerized to 4-7 having tricyclo<2.2.1.0^2,6>heptane skeletons by a -ZnBr2-Zn system in THF.

Full text of DOI:10.1246/bcsj.59.1277

Products guided by the article

Product name:1,2,4:5,6,8-Dimetheno-s-indacene,dodecahydro-, (1R,4S,4aR,5R,8S,8aR,9S,10S)-rel-

Cas No:13002-57-8

R&D Labs maybe for 13002-57-8

ZK Biochem Group Co., Ltd

Contact:+86-532-80762375

Address:No. 6, Hongkong Middle Road, Qingdao, China
Zibo Xiaoguang Chemical Material Co., Ltd

Contact:15954099116

Address:Boshan Development Zone
NINGBO PANGS CHEM INT’L CO.,LTD.

Contact:+86-574-27666845

Address:FLOOR 21,BUILDING NO.11,XIN TIAN DI,NO.689 SHI JI ROAD,NINGBO CHINA
Jiacheng-Chem Enterprises Limited(expird)

Contact:86-571-86711508

Address:19 Floor, CIBC Holley International Building, No. 198,Wuxing Road, Hangzhou, China,310020
XinChem Corporation

Contact:+86 21 34123252

Address:14, 4580 Dushi, Shanghai, China

Relevant to this article

Ring-opening fluorination of α, β-epoxy sulfoxides: A novel synthesis of α-fluoroketones

Doi:10.1248/cpb.38.1798
(1990)
Catalytic Regiodivergent Kinetic Resolution of Allylic Epoxides: A New Entry to Allylic and Homoallylic Alcohols with High Optical Purity

Doi:10.1021/jo035674h
(2004)
THERMAL ANALYSIS OF THE OXALATE HEXAHYDRATES AND DECAHYDRATES OF YTTRIUM AND THE LANTHANIDE ELEMENTS.

Doi:10.1016/0022-5088(80)90222-2
(1980)
Doi:10.1002/ardp.19262641304
(1926)
Synthesis and evaluation of peptidic maleimides as transglutaminase inhibitors

Doi:10.1016/j.bmcl.2006.10.061
(2007)
Design, synthesis, and anti-tumor activities of novel Brevinin-1BYa peptidomimetics

Doi:10.1016/j.bmcl.2021.127831
(2021)

Article Doi