High Diastereofacial Differentiation in Osmium Tetraoxide Catalyzed Dihydroxylation of Acyclic Bis-allylic Compounds

DOI: 10.1021/jo00307a002

Source and publish data:

Journal of Organic Chemistry p. 5424 - 5426 (1990)

Update date:2022-08-02

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Authors:

Saito, Seiki

Morikawa, Yasuhisa

Moriwake, Toshio

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Article abstract of DOI:10.1021/jo00307a002

Bis-allylic compounds such as diethyl (4S,5S)-4,5-bis(tert-butyldimethylsilyl)oxy)-2,6-octadienedioate (1a) exhibit very high diastereoselection in osmiumtetraoxide catalyzed dihydroxylation; a particular ground-state conformation is proposed to be respon

Full text of DOI:10.1021/jo00307a002

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