Journal of Organic Chemistry p. 5424 - 5426 (1990)
Update date:2022-08-02
Topics:
Saito, Seiki
Morikawa, Yasuhisa
Moriwake, Toshio
Bis-allylic compounds such as diethyl (4S,5S)-4,5-bis(tert-butyldimethylsilyl)oxy)-2,6-octadienedioate (1a) exhibit very high diastereoselection in osmiumtetraoxide catalyzed dihydroxylation; a particular ground-state conformation is proposed to be respon
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