Tetrahedron Letters p. 3961 - 3964 (1990)
Update date:2022-09-26
Topics:
Ruel, Rejean
Deslongchamps, Pierre
The synthesis of optically active 14β-hydroxy steroid 9 is reported.This steroid is obtained in only two steps from chiral precursors 6 and 7 via anionic cycloaddition followed by base-catalyzed aldol reaction of tricetone 8.
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Doi:10.1021/ja01228a055
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