Detection of alkyl, alkoxyl, and alkyperoxyl radicals from the thermolysis of azobis(isobutyronitrile) by ESR/spin trapping. Evidence for double spin adducts from liquid-phase chromatography and mass spectroscopy

DOI: 10.1021/ja00179a010

Source and publish data:

Journal of the American Chemical Society p. 8279 - 8284 (1990)

Update date:2022-08-03

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Authors:

Janzen, Edward G.

Krygsman, Peter H.

Lindsay, David A.

Haire, D. Larry

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Article abstract of DOI:10.1021/ja00179a010

The thermolysis of azobis(isobutyronitrile) (AIBN) in the presence of oxygen has been investigated by spin trapping by using α-phenyl N-tert-butyl nitrone (PBN) and 5,5-dimethylpyrroline N-oxide (DMPO). The aminoxyl products identified by ESR and mass spe

Full text of DOI:10.1021/ja00179a010

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