Tetrahedron p. 4303 - 4332 (1990)
Update date:2022-07-31
Topics:
Varardo, Giancarlo
Giumanini, Angelo G.
Strazzolini, Paolo
The reaction between alkyl nitrites, particularly n-butyl nitrite, and tertiary aromatic amines under a variety of experimental conditions promptly yielded products of N-dealkylation-N-nitrosation, ring nitration, ipso-substitution and, occasionally, combinations of these processes.Aminoethers were detected as final products and intermediates on the way to N-nitrosations.Reaction pathways are suggested for some of the observed behaviours on the basis of experimental evidences whereas other alternatives are discarded.
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