Optically Active Ketones as Chiral Auxiliaries in the -Wittig Rearrangement

DOI: 10.1021/jo00003a048

Source and publish data:

Journal of Organic Chemistry p. 1185 - 1191 (1991)

Update date:2022-07-31

Topics:

Authors:

Keegan, David S.

Midland, M. Mark

Werley, Ralph T.

McLoughlin, Jim I.

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Article abstract of DOI:10.1021/jo00003a048

The stereochemical aspects of the <2,3>-Wittig rearrangement of optically active tertiary ally ethers derived from (+)-camphor and (-)-fenchone were investigated.The rearrangement of the (+)-camphor derivative yielded two olefin products in a 70/30 E/Z ra

Full text of DOI:10.1021/jo00003a048

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