Journal of the Chemical Society. Chemical communications p. 882 - 884 (1990)
Update date:2022-08-03
Topics:
Butler, Richard N.
Duffy, J. Paul
Cunningham, D.
McArdle, P.
Burke, Luke A.
Treatment of 1-methyl-1,2,3-triazolium salts with ethoxide gave 2,3-dihydro-1,2,4-triazines via 1,2,5-triazahexa-1,3,5-trienes but the expected 1,2,3-triazolium-1-methanide 1,3-dipoles were not detected and ab initio calculations suggest that they are thermodynamically unfavoured; the X-ray crystal structure of (6a), a dihydro-1,2,4-triazine, is reported.
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