Tetrahedron p. 4653 - 4662 (1990)
Update date:2022-08-05
Topics: Workup Chiral Control Aldol-Type Reaction
Mukaiyama, Teruaki
Kobayashi, Shu
Sano, Tetsuya
Highly enantioselective aldol-type reaction between achiral ketene silyl acetals of acetic acid esters and achiral aldehydes is successfully carried out by the use of a chiral diamine coordinated tin (II) trifluoromethanesulfonate (tin (II) triflate) and tributyltin fluoride.The structure of this new promoter and the mechanism of the present asymmetric aldol-type reaction are discussed.
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Doi:10.1016/0022-1902(81)80334-X
(1981)Doi:10.1002/cjoc.202100259
(2021)Doi:10.1016/S0040-4039(00)97729-3
(1990)Doi:10.1016/0223-5234(90)90118-M
(1990)Doi:10.1016/j.tet.2011.03.050
(2011)Doi:10.1016/0008-6215(90)80014-T
(1990)
