An extremely mild and general method for the stereocontrolled construction of 1,2-cis-glycosidic linkages via S-glycopyranosyl phosphorodiamidimidothioates

DOI: 10.1016/S0040-4039(00)97729-3

Source and publish data:

Tetrahedron Letters p. 4769 - 4772 (1990)

Update date:2022-08-05

Topics: Protecting groups Deprotection Stereocontrol Activation of the Donor

Authors:

Hashimoto, Shun-Ichi

Honda, Takeshi

Ikegami, Shiro

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Article abstract of DOI:10.1016/S0040-4039(00)97729-3

A highly stereocontrolled construction of 1,2-cis-glycosidic linkages under extremely mild reaction conditions has been developed by using S-glycopyranosyl N,N,N′,N′-tetramethyl-N-phenylphosphorodiamidimidothioates with a non-participating O-2-benzyl grou

Full text of DOI:10.1016/S0040-4039(00)97729-3

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