Selective Synthesis of (Z)-1-Ethylidene-2-silylcycloalkanes by Palladium-Catalyzed Hydrosilylation of 1-Vinylcycloalkenes

DOI: 10.1246/cl.1990.1377

Source and publish data:

Chemistry Letters p. 1377 - 1380 (1990)

Update date:2022-08-04

Topics:

Authors:

Hayashi, Tamio

Hengrasmee, Sunantha

Matsumoto, Yonetatsu

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Article abstract of DOI:10.1246/cl.1990.1377

Hydrosilylation of 1-vinylcycloalkenes with methyldichlorosilane in the presence of a palladium catalyst proceeded with high regio- and stereoselectivity to give (Z)-1-ethylidene-2-silylcycloalkanes in high yields.

Full text of DOI:10.1246/cl.1990.1377

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Product name:[5-tert-Butyl-2-eth-(Z)-ylidene-cyclohexyl]-dichloro-methyl-silane

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