Journal of the Chemical Society. Chemical communications p. 1178 - 1179 (1990)
Update date:2022-07-31
Topics:
Bauer, Tomasz
Kozak, Janusz
Chapuis, Christian
Jurczak, Janusz
The highly diastereoselective <4 + 2> cycloaddition of 1-methoxybuta-1,3-diene (3) to (2R)-N-glyoxyloylbornane-10,2-sultam (2) afforded the adduct (4) which was effectively transformed into (4R,6S)-4-hydroxy-6-hydroxymethyltetrahydro-2-pyrone (1), a key synthon for the lactone moiety of compactin and mevinolin.
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