Enantioselective synthesis of the α-pyrone subunit of verrucosidin

DOI: 10.1248/cpb.41.1358

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 1358 - 1361 (1993)

Update date:2022-09-26

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Authors:

Hatakeyama

Ochi Ochi

Takano Takano

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Article abstract of DOI:10.1248/cpb.41.1358

4-Methoxyl-6-[(1S)-1-(trimethylsilyloxy)-1-methyl-2-oxobutyl]-3,5- dimethyl-2H-pyran-2-one (4), a key α-pyrone subunit for the synthesis of verrucosidin (1), has been prepared from 6-ethyl-4-hydroxy-3,5-dimethyl-2H- pyran-2-one (5) in an enantiomerically

Full text of DOI:10.1248/cpb.41.1358

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