A Highly Stereoselective Synthesis of the AB Disaccharide Unit of Olivomycin A

DOI: 10.1021/jo00004a054

Source and publish data:

Journal of Organic Chemistry p. 1649 - 1655 (1991)

Update date:2022-07-30

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Authors:

Roush, William R.

Lin, Xiaofa

Straub, Julie A.

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Article abstract of DOI:10.1021/jo00004a054

A highly stereoselective synthesis of the AB disaccharide (4c) of olivomycin A is described.The synthesis features the double asymmetric allylboration of α,β-dialkoxy aldehyde 8 using tartrate allylboronate (S,S)-9, which provides triol derivative 10 with

Full text of DOI:10.1021/jo00004a054

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