Niederkoordinierte Phosphorverbindungen LVII. Alkali(diphosphaallyl)ferrate, synthese und Reaktionen

DOI: 10.1016/S0022-328X(00)99791-2

Source and publish data:

Journal of Organometallic Chemistry p. 179 - 186 (1987)

Update date:2022-07-29

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Authors:

Appel, R.

Schuhn, W.

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Article abstract of DOI:10.1016/S0022-328X(00)99791-2

Reaction of the diphosphapropene I with Na3Fe(CO)4, or treatment of its lithium salt with Fe(CO)5, affords 1,3-diphosphaallylferrates(-1).Their condensation with alkyl halides or chlorophosphanes yields either the η²,η¹- or η¹,η¹-1,3-diphosphapropene-iron complexes.Protolysis with hydrogen chloride in ether leads via the hydrido-iron species to a stable 1,3-diphosphapropene-iron compound.

Full text of DOI:10.1016/S0022-328X(00)99791-2

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